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Follow these steps:
1). If your desktop dosent have Gtalk shortcut then create a gatlk shortcut on your desktop.
2). Right click on gtalk shortcut and go to properties.
3). appending the parameter /nomutex to the target, like this:"C:\Users\hp\AppData\Roaming\Google\Google Talk\googletalk.exe" /nomutex.
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4). click OK.
Now you can use this shortcut to launch multiple instances of Google Talk log in with different users name and enjoy chatting...
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